Spinel-hosted hydrous silicate mineral inclusions are often observed in dunite and troctolite as well as chromitite. Their origin has been expected as products associated with melt–peridotite reaction, based on the host rock origin. However, the systematics in mineralogical and geochemical features are not yet investigated totally. In this study, we report geochemical variations of the spinel-hosted pargasite inclusions in reacted harzburgite and olivine-rich troctolite collected from Atlantis Massif, an oceanic core complex, in the Mid-Atlantic Ridge. The studied samples are a good example to examine geochemical variations in the inclusions because the origin and geological background of the host rocks have been well constrained, such as the reaction between MORB melt and depleted residual harzburgite beneath the mid-ocean ridge spreading center. The trace-element compositions of the pargasite inclusions are characterized by not only high abundance of incompatible elements but also the LREE and HFSE enrichments. Distinctive trace-element partitioning between the pargasite inclusion and the host-rock clinopyroxene supports that the secondary melt instantaneously formed by the reaction is trapped in spinel and produces inclusion minerals. While the pargasite geochemical features can be interpreted by modal change reaction of residual harzburgite, such as combination of orthopyroxene decomposition and olivine precipitation, degree of the LREE enrichment as well as variation of HREE abundance is controlled by melt/rock ratio in the reaction. The spinel-hosted hydrous inclusion could be embedded evidence indicating melt–peridotite reaction even if reaction signatures in the host rock were hidden by other consequent reactions. 相似文献
Sea levels of different atmosphere–ocean general circulation models (AOGCMs) respond to climate change forcing in different ways, representing a crucial uncertainty in climate change research. We isolate the role of the ocean dynamics in setting the spatial pattern of dynamic sea-level (ζ) change by forcing several AOGCMs with prescribed identical heat, momentum (wind) and freshwater flux perturbations. This method produces a ζ projection spread comparable in magnitude to the spread that results from greenhouse gas forcing, indicating that the differences in ocean model formulation are the cause, rather than diversity in surface flux change. The heat flux change drives most of the global pattern of ζ change, while the momentum and water flux changes cause locally confined features. North Atlantic heat uptake causes large temperature and salinity driven density changes, altering local ocean transport and ζ. The spread between AOGCMs here is caused largely by differences in their regional transport adjustment, which redistributes heat that was already in the ocean prior to perturbation. The geographic details of the ζ change in the North Atlantic are diverse across models, but the underlying dynamic change is similar. In contrast, the heat absorbed by the Southern Ocean does not strongly alter the vertically coherent circulation. The Arctic ζ change is dissimilar across models, owing to differences in passive heat uptake and circulation change. Only the Arctic is strongly affected by nonlinear interactions between the three air-sea flux changes, and these are model specific.
This paper reviews recent progress on the geotectonic evolution of exotic Paleozoic terranes in Southwest Japan, namely the Paleo-Ryoke and Kurosegawa terranes. The Paleo-Ryoke Terrane is composed mainly of Permian granitic rocks with hornfels, mid-Cretaceous high-grade metamorphic rocks associated with granitic rocks, and Upper Cretaceous sedimentary cover. They form nappe structures on the Sambagawa metamorphic rocks. The Permian granitic rocks are correlative with granitic clasts in Permian conglomerates in the South Kitakami Terrane, whereas the mid-Cretaceous rocks are correlative with those in the Abukuma Terrane. This correlation suggests that the elements of Northeast Japan to the northeast of the Tanakura Tectonic Line were connected in between the paired metamorphic belt along the Median Tectonic Line, Southwest Japan. The Kurosegawa Terrane is composed of various Paleozoic rocks with serpentinite and occurs as disrupted bodies bounded by faults in the middle part of the Jurassic Chichibu Terrane accretionary complex. It is correlated with the South Kitakami Terrane in Northeast Japan. The constituents of both terranes are considered to have been originally distributed more closely and overlay the Jurassic accretionary terrane as nappes. The current sporadic occurrence of these terranes can possibly be attributed to the difference in erosion level and later stage depression or transtension along strike-slip faults. The constituents of both exotic terranes, especially the Ordovician granite in the Kurosegawa-South Kitakami Terrane and the Permian granite in the Paleo-Ryoke Terrane provide a significant key to reconstructing these exotic terranes by correlating them with Paleozoic granitoids in the eastern Asia continent. 相似文献
Group II xenoliths, corresponding to the lithology of dunite, wehrlite to olivine clinopyroxenite and olivine websterite to websterite, occur in Pleisto-Holocene alkali basalts from Jeju Island, South Korea. The large grain size (up to 5?mm), moderate mg# [=100?×?Mg/(Mg?+?Fetotal) atomic ratio] of olivine (79–82) and pyroxenes (77–83), and absence of metamorphic textural features indicate that they are cumulates of igneous origin. Based on textural features, mineral equilibria and major and trace element variations, it can be inferred that the studied xenoliths were crystallized from basaltic melts enriched in incompatible trace elements and belong to the Jeju Pleisto-Holocene magma system. They appear to have been emplaced near the present Moho, an estimated 5–8?kbars beneath Jeju Island. Consolidation of cumulates was followed by infiltration of silica-enriched metasomatic melt, producing secondary orthopyroxenes at the expense of olivine. The metasomatic agent appears to have been a silica-enriched residual melt evolved from an initially slightly silica-undersaturated alkali basalt to silica-saturated compositions by fractional crystallization under relatively high pressure conditions. The result of this study indicates that relatively young olivine-bearing cumulates could have been metasomatized by a silica-enriched melt within underplates, suggesting that silica enrichment can occur in intraplate Moho-related rocks as well as in the upper mantle of the subarc area. 相似文献
Ultramafic cumulates, mainly crustal true wehrlites, were discovered and described in the mantle–crust transition zone (MTZ)
and the extremely lower layered gabbro sequence of the Ras Salatit ophiolite, Central Eastern Desert, Egypt. They form either
boudinaged lensoidal tabular bodies or interdigitated layers often concordant with the planolinear fabrics of the Ras Salatit
ophiolite rocks. The contact between wehrlites and the host MTZ dunite or layered gabbro is razor sharp, lobate and/or sinuous,
without chilled margins or any visible deformations. The Ras Salatit wehrlites are orthopyroxene-free and composed mainly
of olivine and clinopyroxene. They are texturally equilibrated and show a characteristic poikilitic texture. Crystallization
order of the Ras Salatit wehrlites is olivine/spinel followed by clinopyroxene with the absence of plagioclase. Olivine and
clinopyroxene of the Ras Salatit wehrlites are compositionally uniform and conspicuously high in Mg#, mostly around 0.93 and
0.92, respectively. Moreover, the clinopyroxene shows low Ti and Al contents coupled with marked depletion in LILE. The calculated
melt in equilibrium with clinopyroxene from the Ras Salatit wehrlites is largely similar to lavas from the Izu-Bonin forearc.
Given the above characteristics, the Ras Salatit wehrlites were produced by crystal accumulation from a hydrous depleted basaltic/tholeiitic
melt corresponding to temperatures between 1,000 and 1,100°C at the oceanic crustal pressure (~2 kbar). The involved hydrous
tholeiitic melt has been probably formed by fluid-assisted partial melting of a refractory mantle source (similar to the underlying
harzburgites) in a somewhat shallow sub-arc environment. 相似文献
The structural changes of synthetic opal by heat treatment up to 1,400 °C were investigated using scanning electron microscopy, X-ray diffraction, and Fourier transform infrared and Raman spectroscopies. The results indicate that the dehydration and condensation of silanol in opal are very important factors in the structural evolution of heat-treated synthetic opal. Synthetic opal releases water molecules and silanols by heat treatment up to 400 °C, where the dehydration of silanol may lead to the condensation of a new Si–O–Si network comprising a four-membered ring structure of SiO4 tetrahedra, even at 400 °C. Above 600 °C, water molecules are lost and the opal surface and internal silanol molecules are completely dehydrated by heat effect, and the medium-temperature range structure of opal may begin to thermally reconstruct to six-membered rings of SiO4 tetrahedra. Above 1,000 °C, the opal structure almost approaches that of silica glass with an average structure of six-membered rings. Above 1,200 °C, the opal changes to low-cristobalite; however, minor evidence of low-tridymite stacking was evident after heat treatment at 1,400 °C. 相似文献
Utilization of cheap renewable carbon feedstock for polyhydroxyalkanoate (PHA) production not only brings down its production cost but also ensures sustainability. The scope of this study was to evaluate the potential of sap extracted from felled oil palm trunk (OPT) as a novel inexpensive renewable carbon source for PHA production. OPT sap was found to be nutritionally rich and contained various fermentable sugars (5.5% w/v) as its major constituent. Termite gut isolate, Bacillus megaterium MC1 grew profoundly in mineral medium with OPT sap as carbon source and a cell density of 10.9 g/L was attained after 16 h of cultivation in shake flask cultures. A maximum poly‐3‐hydroxybutyrate [P(3HB)] content (% cell dry weight; CDW) of 30 wt% and a P(3HB) concentration of 3.28 g/L was recorded. Additionally, OPT sap extracted from younger tree trunks with prolonged storage had higher sugar content (10.8% w/v) and, when used as a growth medium without the addition of any nutrients, supported bacterial growth comparable to commercially available media. 相似文献